Synthesis And Evaluation Of Metal-Doped Rice Husk Silica For Iodine Vapor Capture

Authors

  • Niyazova Dilnoza Bakhtiyorovna Researcher (PhD), Institute of General and Inorganic Chemistry, ASc RUz, Tashkent, Uzbekistan
  • Mamajonov Bakhodirjon Madaminovich Applicant (PhD Seeker), Namangan Institute of Engineering and Technology, Namangan, Uzbekistan
  • Khoshimov Shakhrom Mansurovich Doctoral student (DSc), Institute of General and Inorganic Chemistry, ASc RUz, Tashkent, Uzbekistan
  • Abdikamalova Aziza Bakhtiyarovna Chief researcher, Institute of General and Inorganic Chemistry, ASc RUz, Doctor of Chemical Sciences, Professor, Uzbekistan
  • Eshmetov Izzat Dusimbatovich Chief researcher, Institute of General and Inorganic Chemistry, ASc RUz, Doctor of Chemical Sciences, Professor, Uzbekistan
  • Mamataliev Nozim Nimadjonovich Chief researcher, Institute of General and Inorganic Chemistry, ASc RUz, Doctor of Chemical Sciences, Uzbekistan
  • Alisher Maksetbaevich Kalbaev Junior Researcher, PhD, Institute of General and Inorganic Chemistry, ASc RUz, Tashkent, Republic of Uzbekistan, Uzbekistan

Keywords:

Rice husk silica, iodine capture, metal-doped sorbents

Abstract

Amorphous silica was synthesized from rice husk and doped with Ag, Cu, Zn, or Bi to develop iodine sorbents. The resulting metal-loaded silica materials, produced via thermal treatment after wet impregnation, were tested for iodine vapor uptake at 25 °C for 1 hour. Bismuth- and copper-modified silica achieved the highest capacities (0.5–0.6 g I2/g), outperforming silver (0.2 g/g) and zinc (0.15 g/g). The enhanced performance stems from chemisorption via metal iodide formation (AgI, CuI, ZnI2, BiI3). These results align with literature values and demonstrate a sustainable route to efficient iodine capture using low-cost rice husk silica combined with targeted metal additives.

References

Li B., et al. Molecular iodine capture by covalent organic frameworks // Molecules. – 2022. – Vol. 27. – P. 9045.

Zhang F., et al. Polymorphic covalent organic frameworks: molecularly defined pore structures and iodine adsorption property // Molecules. – 2023. – Vol. 28. – P. 449.

Chen Y., et al. Cu/Bi–NC composites derived from bimetallic MOFs for efficient and selective capture of iodine // Processes. – 2023. – Vol. 13. – P. 2678.

Chen W., et al. Rapid and selective adsorption of iodide and iodate ions by hierarchical porous materials // Nanomaterials. – 2023. – Vol. 13. – P. 576.

Wang Z., et al. Metal–organic framework-polyethersulfone composite membrane for iodine capture // Polymers. – 2020. – Vol. 12. – P. 2309.

Toro P., et al. Transforming rice husk ash into road safety: a sustainable approach to glass microsphere production // Materials. – 2019. – Vol. 8. – P. 93.

Lim W. S., et al. Characterization of rice husk-based adsorbent for iodine and methylene blue removal // Processes. – 2023. – Vol. 13. – P. 2748.

Xu X., et al. High capacity adsorption of iodine gas by Ag⁰@C/SiO2 derived from rice husk // Carbon Letters. – 2021. – Vol. 31. – P. 29–40.

Shi W., et al. Synthesis of silver-impregnated magnetite mesoporous silica composites for removing iodide in aqueous solution // Toxics. – 2021. – Vol. 9. – P. 175.

Li J., et al. Improved utilization of Cu⁰ for efficient adsorption of iodine in gas phase // Chemical Engineering Journal. – 2024. – Vol. 460. – P. 141915.

Li Y., et al. Synthesis and characterization of silver-modified nanoporous silica materials for enhanced iodine removal // Nanomaterials. – 2023. – Vol. 14. – P. 1143.

Zhang Q., et al. Recent advances in the removal of radioactive iodine by bismuth-based materials // Frontiers in Chemistry. – 2023. – Vol. 11. – P. 1122484.

Chen L., et al. Efficient removal of radioactive iodine anions using δ-Bi2O3/MOF-808 through photo-oxidation and adsorption: performance evaluation and mechanistic insights // (Preprint, 2023).

Seitnazarova O., Kalbaev A., Mamataliev N., Abdikamalova A., Najimova N. Structural features of montmorillonite-surfactant systems: influence of surfactant packing density and montmorillonite surface nature // Journal of Chemical Technology and Metallurgy. – 2025. – Vol. 60. – No. 1. – P. 43–62.

Seitnazarova O.M., et al. Organobentonites synthesis and their sorption characteristics research // Palarch’s Journal of Archaeology of Egypt/Egyptology. – 2020. – Vol. 17. – No. 6.

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Published

2025-11-30

How to Cite

Niyazova Dilnoza Bakhtiyorovna, Mamajonov Bakhodirjon Madaminovich, Khoshimov Shakhrom Mansurovich, Abdikamalova Aziza Bakhtiyarovna, Eshmetov Izzat Dusimbatovich, Mamataliev Nozim Nimadjonovich, & Alisher Maksetbaevich Kalbaev. (2025). Synthesis And Evaluation Of Metal-Doped Rice Husk Silica For Iodine Vapor Capture. Emerging Frontiers Library for The American Journal of Applied Sciences, 7(11), 100–107. Retrieved from http://emergingsociety.org/index.php/efltajas/article/view/911

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